(1R)-(+)-2,10-Camphorsultam
右旋樟脑磺内酰胺

  • CAS号:108448-77-7
  • MDL编号:MFCD00151762
  • 分子式:C10H17NO2S
  • 分子量:215.31
  • 韶远库存批次纯度:99.0%, 99.8%
  • optical purity:≥ 97.0%
  • 相关药品名称:-
  • 产品分类: 高端化学品 > 有机合成砌块 > 羰基化合物 > 酰胺类 ; 高端化学品 > 手性化合物 > 手性试剂/助剂 ;
  • * 韶远所有产品仅供科研使用
品牌 货号 纯度标准 包装 价格/优惠价 折扣价 特价 上海 济南 成都 武汉 天津 数量1 购买
韶远 SY004517 >98% 1g 29.00/0 - 4 4 - 1 -
韶远 SY004517 >98% 5g 49.00/0 - 2 1 1 - 1
韶远 SY004517 >98% 10g 89.00/0 - 1 2 1 - -
韶远 SY004517 >98% 25g 189.00/0 - 3 3 - - -
韶远 SY004517 >98% 100g 751.00/0 - - - - - -
韶远 SY004517 >98% 1000g POA/0 POA - - - - -
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Versatile chiral auxiliary introduced by Oppolzer. Review: Tetrahedron, 49, 293 (1993).
N-Acryloyl derivatives undergo enantioselective cycloaddition reactions: Helv. Chim. Acta, 67, 1397 (1984); Tetrahedron, 43, 1969 (1987). Hydrogenation of N-acryloyl derivatives proceeds with high diastereoselectivity: Tetrahedron Lett., 27, 183 (1986); Helv. Chim. Acta, 69, 1542 (1986), 69, 1817 (1986); 70, 1666 (1987). Induces asymmetric conjugate addition of Grignard reagents to N-acryloyl derivatives: Helv. Chim. Acta, 70, 2201 (1987). In the presence of strong bases, N-acyl derivatives undergo stereoselective alkylation: Tetrahedron Lett., 30, 5603 (1989); or aldol-type condensation reactions with aldehydes: J. Am. Chem. Soc., 112, 2767 (1990); Tetrahedron Lett., 32, 61 (1991).
Chiral auxiliary for the asymmetric Baylis-Hillman reaction: J. Am. Chem. Soc., 119, 4317 (1997).
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